Burdge/Overby, Chemistry: Atoms First, 2e FM | Page 33
CONTENTS xxxiii
18.5 Spontaneity of Redox Reactions Under Conditions Other Than Standard
State?787
• The Nernst Equation? 787 • Concentration Cells? 789
18.6 Batteries?792
• Dry Cells and Alkaline Batteries? 792 • Lead Storage Batteries? 793
• Lithium-Ion Batteries? 793 • Fuel Cells? 793
18.7 Electrolysis?795
• Electrolysis of Molten Sodium Chloride? 795 • Electrolysis of Water? 796
• Electrolysis of an Aqueous Sodium Chloride Solution? 796 • Quantitative
Applications of Electrolysis? 797
18.8 Corrosion?800
19
Chemical Kinetics? 814
19.1Reaction Rates? 815
19.2Collision Theory of Chemical Reactions? 815
19.3Measuring Reaction Progress and Expressing Reaction Rate? 817
19.4
19.5
19.6
19.7
19.8
20
• Average Reaction Rate? 817 • Instantaneous Rate? 821 • Stoichiometry
and Reaction Rate? 824
Dependence of Reaction Rate on Reactant Concentration? 827
• The Rate Law? 827 • Experimental Determination of the Rate Law? 828
Dependence of Reactant Concentration on Time? 832
• First-Order Reactions? 832 • Second-Order Reactions? 838
Dependence of Reaction Rate on Temperature? 841
• The Arrhenius Equation? 841 • Thinking Outside the Box: Surface Area? 846
Reaction Mechanisms? 847
• Elementary Reactions? 847 • Rate-Determining Step? 848 • Mechanisms with
a Fast First Step? 852 • Experimental Support for Reaction Mechanisms? 854
Catalysis?855
• Heterogeneous Catalysis? 856 • Homogeneous Catalysis? 856
• Enzymes: Biological Catalysts? 857
Nuclear Chemistry? 874
20.1 Nuclei and Nuclear Reactions? 875
20.2 Nuclear Stability? 877
• Types of Nuclear Decay? 877 • Nuclear Binding Energy? 878
20.3 Natural Radioactivity? 881
• Kinetics of Radioactive Decay? 881 • Dating Based on Radioactive Decay? 882
20.4 Nuclear Transmutation? 885
20.5 Nuclear Fission? 887
20.6 Nuclear Fusion? 893
20.7 Uses of Isotopes? 895
• Chemical Analysis? 895 • Thinking Outside the Box: Nuclear Medicine? 896
• Isotopes in Medicine? 896
20.8 Biological Effects of Radiation? 897
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