RACA Journal June 2019 | Page 54

Getting Technical Modern rinks have a specific procedure for preparing the surface. With the refrigeration plant running so that the pipes are cold, a thin layer of water is sprayed on the concrete to seal and level it. This thin layer is painted white or pale blue for better contrast so that markings necessary for sports, along with logos or other decorations put onto this surface show up clearly through further subsequent upper layers. The ice sheet is built progressively in 1–2mm thick layers up to a total thickness of between 20 – 35mm. The ice sheet is built progressively in 1–2mm thick layers up to a total thickness of between 20–35mm. Total volumes of water used usually amount to between 40 000 and 50 000 litres, thereby making 40–50 metric tons of ice. Ice temperatures required are only a few degrees below freezing. The general temperature level for recreational skating is -3°C which is also widely used by figure skaters and hockey players for training. For competitive displays and hockey matches, however, a “faster” ice surface is created by reducing ice temperature to between -5 to -6°C. WATER QUALITY REQUIRED FOR ICE MAKING Quality ice can only be made from water that is pure — but not too pure. Demineralisation and filtration of the water used to build ice sheets is now generally done for the removal of impurities such as suspended solids and gases. Ice will always try to freeze as pure as it is able to. Impurities in the ice may result in a friable surface on top, which is the frozen equivalent Figure 2: A modern “Zamboni” type ice surface treatment machine. 52 RACA Journal I June 2019 of foam or froth forming an impure surface layer which, from a skating point of view, is known as “really poor ice”. This impure layer also puts more loading on the refrigeration system than purer, denser ice does. Purer, denser ice has greater structural integrity and thus can withstand the rigours of skating manoeuvres and ice hockey as a thinner sheet. Also, it is much less difficult (and less costly) to keep pure ice frozen. One of the most common contaminants in water inhibiting the formation of quality ice is trapped air bubbles. University of California, Berkeley chemistry professor Gabor Somorjai, author of Introduction to Surface Chemistry and Catalysis, has demonstrated that there is always a layer of water on the surface of ice regardless of its temperature. For a number of years before Somorjai’s research, there was debate as to whether pressure or friction created the water lubricant that was believed to be required for skating. Most scientists seemed to think that it was pressure. According to Somorjai’s findings this is not the case. So what does a skate slide on? Somorjai proposes that it slides on vibrating molecules. Professor Somorjai and his team used the most up-to-date methods to examine the surface structure and composition of the atoms and molecules that make up ice, and what they found was surprising. Initially, they found that the structure was an almost impossible one, indicating that every second water molecule on the surface was missing. Since that was not realistically possible, the team expanded their research programme which determined that the “missing” water [or ice] molecules were in fact there, but vibrating so rapidly that they were not visible to the technique currently being used. Finally, after further study, the team found that these molecules behave like a liquid, but they only move up and down and not from side to side on the surface of the ice. This was an important distinction. If the atoms moved side to side, the “liquid-like” layer would literally become liquid, which is what happens when the temperature rises above 0°C. This “liquid-like” layer is now thought to be what makes ice slippery and provides skaters with a lubricant on which to glide, not the “melt water” many have long believed results from skate blade pressure. The layer becomes even thinner at extremely cold temperatures and thickens as ice approaches the melting point – each extreme reducing “skate-glide” accordingly. Air bubbles amplify this water/ice interface effect, resulting in slow ice at both normal and colder temperatures. The method used to reduce trapped air bubbles sufficiently to avoid their adverse effects on ice is the same as for obtaining clear shiny ice cubes in domestic or commercial refrigerators. Start with good quality water and heat it up to around 60°C before beginning the refrigerating process. Ice rink operators try to reduce costs by heating the water up to a few degrees less and normally find that about 55°C works www.hvacronline.co.za