Third Cuise of the U.K. Ocean Acidification Programme in the Southern Seas | Page 15

All this is not to say that if we sustain 400 ppm in the atmosphere we are destined to have a world like the Oligocene , as other factors may have contributed to global warmth then . Other greenhouse gases especially methane may have contributed to global warmth , as may the very different pattern of ocean and atmospheric circulation . We cannot use the past to generate simplistic links and predictions or try to prove or disprove the greenhouse effect which is the realm of modern atmospheric physics .
But if there is one simple message it is this : The geological record gives us no reassurance that 400 ppm of CO 2 in the atmosphere is a safe level to maintain in the long term ( safe , in terms of preserving our continental ice caps ). Only climate models with high sensitivity to CO 2 seem to be able to capture the main features of past geological warm climates like the Oligocene and Miocene . And of course halting pCO 2 at 400 ppm is not going to happen .
References
Allen , K . A . and Hönisch , B . 2012 . The planktic foraminiferal B / Ca proxy for seawater carbonate chemistry : a critical evaluation . Earth & Planetary Science Letters , 345-348 , 203-212 .
Badger , M . et al . 2013 . CO2 drawdown following the middle Miocene expansion of the Antarctic ice sheet . Paleoceanography , 28 , 42-53 .
Bartoli , G ., Hönisch , H . and Zeebe , R . E . 2011 . Atmospheric CO 2 decline during the Pliocene intensification of Northern Hemisphere glaciation . Paleoceanography , 26 , PA4213 .
Foster , G . L ., Lear , C . H ., and Rae , J . W . B . . 2012 . The evolution of pCO 2 , ice volume and climate during the middle Miocene . Earth & Planetary Science Letters , 341-344 , 243-254 .
Klochko , K . et al . 2006 . Experimental measurement of boron isotope fractionation in seawater . Earth & Planetary Science Letters , 248 , 261-270 .
Kürschner , W . M . et al . 1996 . Oak leaves as biosensors of late Neogene and early Pleistocene paleoatmopsheric CO 2 concentrations . Marine Micrpaleontology , 27 , 299-312 .
Lowenstein , T . K . and Demicco , R . V . 2006 . Elevated Eocene atmospheric CO 2 and its subsequent decline . Science , 313 , 1928
Lüthi , D . et al . 2008 . High resolution carbon dioxide concentration record 650 , 000-800,000 years before present . Nature , 453 , 379-382 .
Pagani , M ., Freeman , K . H . and Arthur , M . A . 1999 . Late Miocene atmospheric CO 2 concentrations and the expansion of C 4 grasses . Science , 285 , 876-879 .
Pagani , M . et al . 2005 . Marked decline in atmospheric carbon dioxide concentrations during the Paleogene . Science , 309 , 600-603 .
Pagani , M . et al . 2010 . High Earth-system climate sensitivity determined from Pliocene carbon dioxide concentrations . Nature Geoscience , 3 , 27-30 .
Palmer , M . R . and Pearson , P . N ., 2003 . A 23,000-year record of surface water pH and pCO 2 in the western equatorial Pacific Ocean . Science 300 : 480-482 .
Pearson , P . N . and Palmer , M . R ., 1999 . Middle Eocene seawater pH and atmospheric CO 2 levels . Science , 284 : 1824-1826 .
Pearson , P . N . and Palmer , M . R . 2000 . Atmospheric carbon dioxide over the past 60 million years . Nature , 406 : 695-699 .
Pearson , P . N ., Foster , G . L . and Wade , B . S . 2009 . Atmospheric carbon dioxide through the Eocene - Oligocene climate transition . Nature 461 : 1110-1113 . doi : 10.1038 / nature 08447Raymo et al . 1996