Speciality Chemicals Magazine MAY / JUN 2023 | Page 23

CATALYSTS
Industrial distillation plant
Market trends & drivers
The key factors propelling the expansion of the catalyst treatment market include the following : 1 . Growing demand for more efficient and sustainable chemical processes : Homogeneous catalysts offer higher selectivity and better conversion rates compared to their heterogeneous counterparts , leading to increased demand in various industries 2 . Technological advances : Innovations in catalyst design , synthesis and characterisation have enabled the development of novel catalysts with improved performance , further propelling the market ’ s growth 3 . An increasing focus on environmental regulations : As the emphasis on reducing environmental pollution grows , companies are adopting homogeneous catalysts to create eco-friendly processes that comply with regulatory standards
Treatment route factors & technology options
Several factors influence the choice of treatment routes and technology partners , such as solvent selection , co-catalyst choice and the overall complexity of the material . Based on these factors , three primary technology options are available for catalyst recovery : scavengers , advanced distillation and advanced thermal treatment . Figure 1 summarises the recovery routes .
Scavengers are functionalised materials ( polymers or silicas ) that selectively bind to the precious metal in solution . These are often used in fixed-bed columns , which can be installed on the processing site or treated off-site as a service .
Advanced distillation is a technique in which lower boiling point solvents are removed , leaving a concentrate or tar . Running a distillation process with the goal of recovering precious metals differs from standard solvent separations . Special conditions and additives are required to minimise losses .
Advanced thermal treatment involves removing water and oxidising carbon-containing compounds to produce a rich ash . This process has significant complexities to ensure controlled oxidation . Off-gases must be treated by a suitable gas treatment plant to meet required emission standards . Some advanced thermal treatment systems can even process materials containing fluorine and iodine through proprietary technology development .
Catalyst characteristics
There are a number of characteristics that influence the optimum treatment route . These include the solvent used and the co-catalyst and segregation .
The choice of solvent is crucial . For example , solvents like tetrahydrofuran are undesirable for advanced thermal treatment due to their ability to form explosive peroxides , making it difficult to separate the catalyst from the solvent . On the other hand , low boiling point , unreactive solvents can be distilled off more efficiently .
MAY / JUN 2023 SPECCHEMONLINE . COM
23