Speciality Chemicals Magazine MAY / JUN 2021 | Page 40

Tensile strength [ Mpa ]

‣ 140.0 130.0 120.0 110.0 100.0 90.0 80.0 70.0 60.0

1 PBT 30 % GF
1 - Ref PA 6,6 30 % GF
2 - Brominated PS , ATO epoxy , ATO
3 - Brominated PS , no epoxy ATO , no ATO
4 - Brominated Epoxy , TO polyacrylate , ATO
5 - Brominated epoxy , no ATO
Polyacrylate , no ATO
6 - DEPAL
50.0
Reference 1 Round round 1 2 Round round 2 3 Round round 3 4 Round round 4
Reference
Recycling
Impact curve
Impact J / m
100.0
90.0
80.0
70.0
60.0
50.0
40.0
30.0
20.0
10.0
PA 6,6
With UL-94 V0 , GFR PA 6,6 , the methodology employed was based on five cycles of concomitant injection moulding and mechanical recycling . The first cycle involved freshly compounded material , while the following four cycles were performed by mixing 50 % of the initial , fresh compound with 50 % recycled material from the previous cycle . Six 30 % GFR PA 6,6 formulations were tested : 1 . No FR 2 . Brominated polystyrene & antimony trioxide ( ATO ) as synergist
3 . Brominated polystyrene & alternative synergist , ATO-free
4 . High molecular weight ( MW ) brominated epoxy & ATO as synergist
5 . High MW brominated & alternative synergist , ATO-free
6 . Diethyl phosphinate aluminum ( DEPAL ) FR
0.0
Reference
1 Round round1 2 Round round 2 3 Round round3
4 Round round4
Recycling
Figure 2 – Recycling performance of different flame retardant systems for 30 % GFR PBT : Impact strength ( a ) & tensile strength ( b )
40 SPECIALITY CHEMICALS MAGAZINE ESTABLISHED 1981