Speciality Chemicals Magazine JUL / AUG 2026 | Page 25

New Phosphine Ligand for Ni catalyst

New Phosphine Ligand for Ni catalyst

Triisobutylenediphenylphosphine
Abbreviation: TIBDPP
Chemical Name: 2,2,6,6-Tetramethyl-4-methylene heptyldiphenylphosphine 2-( 2,2’-Dimethylpropyl)-4,4’-dimethyl-1-pentyldiphenylphosphane
CAS. RN @
: 3108425-95-9
Molecular Weight: 354.5
Physical Form
: Colorless to clear yellow liquid
Density( 25 ℃)
: 0.948g / ml
Boiling Point
: no data
Melting Point
:-16 ℃
Purity / Content
: ≧ 95.0 %
※ This product is manufactured and sold under a license agreement with ENEOS Corporation.
* TIBDPP offers air stability comparable to TPP and is easy to handle as a liquid phosphine.
Ni-phosphine catalysis for Suzuki-Miyaura cross-coupling ※ 1

HOKKO

TIBDPP
Cy tyrannoPhos
Contact:
Hokko Chemical Industry Co., Ltd. Fine Chemicals Marketing Department
TPP
TCHP
Sumitomo Fudosan Nihonbashi Building 1-5-4, Nihonbashi Honcho, Chuo-Ku, Tokyo 103-8341, Japan TEL: + 81-3-3279-5142 FAX:+ 81-3-3279-3857
※ 1 K. Matsubara *, K. Miyoshi, Y. Shibasaki, M. Moriguchi, Y. Koga, T. Takashima, T. Sato, Y. Asai, Y. Hakozaki, Y. Tago, Org. Lett. 2025, 27, 49, 13432 – 13436
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