Metal Bulletin Research STRATEGIC OUTLOOK FOR THE PRIMARY BATTERY 2 | Page 2
Battery Metals
3 Battery Chemistry
Table 3.1: Example Elemental Compositions of Various Battery Types
Battery Type
Li-ion
Ni-Cadmium
Alkaline
Ni-Metal Hydride
Lead-Acid
Zinc-air
Zinc-carbon
Ni
neg.
22%
1%
35%
neg.
neg.
neg.
Zn
neg.
neg.
15%
1%
neg.
35%
20%
Li
3%
neg.
neg.
neg.
neg.
neg.
neg.
Pb
neg.
neg.
neg.
neg.
65%
neg.
neg.
Cd
neg.
15%
neg.
neg.
neg.
neg.
neg.
Co
18%
neg.
neg.
4%
neg.
neg.
neg.
Fe
22%
35%
25%
20%
neg.
42%
17%
Source: MBR
The primary industrial metals used in batteries are cobalt, zinc, nickel, lead and lithium. Manganese, cadmium and iron are
also important. For the primary industrial metals, cobalt typically has the highest price per tonne, followed by nickel, lithium
and then lead and zinc. Because lead and zinc often occur together geologically, they are often mined together, and thus
the markets for both metals are heavily correlated.
Furthermore, there are multiple types of battery electrolyte. The following table shows the types of electrolytes used in the
batteries covered in this study.
Table 3.2: Common Electrolytes Used in Various Battery Types
Battery Type
Li-ion
Ni-Cadmium
Alkaline
Ni-Metal Hydride
Lead-Acid
Zinc-Bromine
Zinc-Cerium
Zinc-Air
Zinc-Carbon
Electrolyte
Lithium percholate, lithium hexaflourophosphate, lithium tetraflouroborate, organic solvents
Potassium hydroxide
Potassium hydroxide
Potassium hydroxide, manganese dioxide
Sulphuric acid
Aqueous zinc, aqueous bromine
Methanesulfonic acid
Potassium hydroxide
Zinc chloride, ammonium chloride
Source: MBR
While these electrolytes are a significant raw material for battery manufacturing, they typically do not have the same
economic impact on the use of various battery types as the metallic components that go into their construction.
3.2 Lead-Acid
The lead-acid battery represents the oldest type of rechargeable battery and is the traditional battery used in combustion
engine vehicles. These are incredibly hardy batteries, capable of starting cars in even the most extreme conditions, but their
weight and the trade-off between power and durability has prevented their widespread use in the hybrid and electric vehicle
market. They use sulphuric acid for an electrolyte, porous lead for an anode and lead-dioxide for a cathode.
The main advantage of lead batteries is price, as lead is relatively cheap, and a huge infrastructure already exists to make
lead-acid batteries. Le Y\