Lubezine Volume 8 * NOVEMBER 2013 - JANUARY 2014 | Page 26

TECHNOLOGY FEATURE mixture and water vapour and settles for about half an hour. The grease mixture is recycled continuously from the bottom of the dehydration zone with the pressure up to 10-200 psi. Base oil is added in the grease mixture at lower temperature to enhance cooling, after which it may be packaged. Grease Trends There are several trends which are affecting grease market. Years ago, we had a slight shift from soda-based grease to calcium.Today, the majority of grease in use is Lithium based. The market is, however, witnessing a shift to calcium sulphonate due to global scarcity of lithium and the good performance of this calcium sulphonate soap. Shift to polymer and synthetic base oils are also taking place across the world. In additives, there is a slight movement toward such novel metals as bismuth, which are more environment-friendly than Zinc ,with better synergy with Sulphur type additive especially for EP grease. On market side, the market is unfortunately suffering from lack of knowledge and information transfer as well as price sensitivity. These are the main drivers for selecting grease which have also influenced an increase in circulation of cheap grease made by non suitable soap , besides recycled base oils into the market. This compromised quality greases are corrosive and non suitable for machineries. One other trend is the growing acceptance of transparent type of grease which is now available in the market. Whilst transparency does not imply any premium quality, the grease can have equal performance with general grease, if manufactured the right way, with its advantage being high aesthetic value. . LUBRICANT PROPERTIES Conversations on Viscometrics O ne of the resource persons at a training I attended a while ago observed that perhaps the best way to explain something is to By Samuel start by stating Macharia what it is not. I agree with him to some extent. But alive to the difficulty that may be involved in starting from describing what viscosity is not, without getting into a conundrum, I will start by saying what it is. Considering the basic elements that explain viscosity, the most basic definition of viscosity is the measure of a fluid’s resistance to flow. And so on viscosity, including all the derivatives that come from that word, at the back of your mind I would want you to have a mental perception of viscosity as resistance to flow. Or – to put it in another way – a liquid’s resistance capacity to flow. Viscosity is arguably the most important property of a lubricant, holding many other factors constant, and depending on the perspective from which you look at it. In a discussion I initiated within a group on Linked In , there was a wide range of views on what viscosity is – and what it is not. Contributing to the discussion, Toby Taylor described viscosity as a physical feature that sadly does not describe what the oil is used for. Excessive Technicality While Taylor’s assertion is true, it also highlights a fundamental lubricant-user information gap, based on the standard descriptions used by oil companies worldwide to describe lubricant application purposes. Understanding viscosity would go a long way to aid the public’s understanding of lubricant applications, away from oil 24 marketers’ intricate descriptions by use of excessive technicality with an aim limited to marketing lubrication products. Viscosity at the point of lubrication is the most important of the specifications but not the only consideration. You cannot isolate this one important factor and ignore the rest, because a lubricant will interact with a dynamic environment. Earlier, I mentioned the term Viscometry which is the Science of measuring viscosity. In other words, of or relating to the measurement of viscosity. Viscosity can be measured in terms of Absolute Viscosity (Centripoise cPs), resistance to flow and shear or by Kinematic viscosity (Centistoke cSt) resistance to flow by shear forces of gravity. Viscosity with Temperature This brings me to the next viscosity derivative: Viscosity Index, a measure of a lubricant’s change in viscosity with temperature. Normally, viscosity decreases with increase in temperature and viceversa. Don McNeil stated in the Linked In discussion, that this behaviour is defined as an arbitrary number assigned as a measure of the constancy of the viscosity of lubricating oil with change of temperature, with higher numbers indicating viscosities that change little with temperature. It is simply a scale to indicate the viscosity change of oils relative to temperature. The most basic definition of viscosity is the measure of a fluid’s resistance to flow LUBEZINE MAGAZINE | November 2013-January 2014