Ispectrum Magazine Ispectrum Magazine #14 | Page 35

The first step from combined temperature / pressure of the amorphous glass matrix will be formation of Cesium silicate. crystal X-ray diffraction (space group P 6¯ 2m, a = 9.578(5) Å, c = 4.155(5) Å, Z = 0.5, 269 F(hkl), R = 0.0424) Ref to Original Russian Text © A.E. Lapshin, N.V. Borisova, V.M. Ushakov, Yu.F. Shepelev, 2006, published in Zhurnal Neorganicheskoi Khimii, 2006, Vol. 51, No. 11, pp. 1804–1808). The excess Oxygen amount from the original Cesium oxide will be consumed by the formation of water vapor with the available Hydrogen from HLW. Once formed, the Cesium silicate undergoes a stage of collapsing during the decay transition – a process already determined in Nuclear Waste science. It is very important The next step will be to recognize the signifiThe required Oxygen cant space differences the transitional formaatom will come ini- along the Crystalline tion of Barium Silicate, coming from the Cesium tially from the Cesium lattice vectors. decay in Cesium oxide in the HLW or Silicate. Silicon dioxide packets in the glass. During this crystalline lattice formation, the newly formed Cesium Silicate will require additional space inside the amorphous glass matrix. This results in a rearrangement of atoms’ positions in the much larger Example of initial Cesium Oxide cluster lattice compared to the amorphous one (single34