IM 2019 August 19 | Page 48

GOLD EXTRACTION matching leach strategies to source characteristics’ paper at the recent ALTA 2019 conference, in Australia. He said: “The gold industry has been supporting research into alternative lixiviants over a number of decades. However, it may sometimes appear to the casual observer that the industry is no closer now than it was 20 years ago to implementing a feasible solution at multiple sites.” Eksteen continued: “Often the problem lies in the fact that one-size-fits-all lixiviants are sought and it is clear…such a panacea does not exist. Ore mineralogy and chemistry, environmental conditions and water availability, mobilisation of toxic deleterious elements and creation of toxic by-products remain challenges, over and above the general required attributes such as sufficiently fast kinetics, low reagent consumption, low reagent price, reagent and gold complex stability, and the need to recycle reagents, which mostly involve expensive solid- liquid separation equipment.” DST believes it has devised a new technology, the CLEVR Process™, that can have wide-scale appeal. The cyanide alternative produces no toxic liquid or gaseous effluents, and generates solid residues that are inert, stable and non-acid generating, according to the company. The process uses sodium hypochlorite with a catalytic amount of sodium hypobromite in acidic conditions to put the gold into solution. “Contact time is short, and the process operates in a closed loop,” DST says, adding that all chemicals are recycled within the circuit, and sea water is also suitable where available. DST has opened the number of applications suitable for CLEVR by introducing, depending on the nature of the mineral, a pre-treatment step prior to gold extraction. Howlett provides an example: “One of the applications requiring pre-treatment might be if you have a high sulphur content in the concentrate. What we would do is remove the sulphur first and create either a sulphuric acid or gypsum using the sulphur – either as an industrial product or a benign tailing.” Taking such a route with high sulphur ores allows companies to remove the sulphur completely before gold extraction takes place, leading to “non-acid leaching tailings”, Howlett said; avoiding another potential environmental liability. This isn’t where the benefits to using CLEVR end, according to the company. “DST's CLEVR Process creates no liquid effluent, which is unlike the cyanide process that requires significant wastewater handling and treatment,” DST said. “We don’t have a liquid tailings pond that can fail,” Howlett explained. This could be of huge benefit to mining companies out there not only struggling to seek permits for cyanide use but also facing opposition to the use of wet tailings dams. CLEVR’s gold recoveries are, generally, in line with those produced by cyanide, according to Howlett, but have outperformed its fellow lixiviant in certain tests. DST has been able to validate these results not only in the lab, but also at a 15 t/d demonstration plant in Thetford Mines, Quebec. Originally commissioned in 2015, a first demonstration campaign, completed in early DST’s CLEVR Process uses sodium hypochlorite with a catalytic amount of sodium hypobromite in acidic conditions to put the gold into solution 2016, saw DST process a total of 170 t of a gold- and copper-bearing refractory pyrite concentrate from a region where the use of cyanide is restricted. The program demonstrated that the CLEVR Process had an average extraction yield 14% higher than cyanidation, with results of up to 81% gold recovery, the company said. And, the company has recently received a mandate from a Chinese customer to continue testing of the CLEVR Process, with a 30-kg sample of mineralised material already delivered to DST’s Quebec facility. “The goal of this work is to demonstrate that its proprietary CLEVR Process can extract gold at a rate of 95% or better,” DST said. DST previously completed analysis of smaller samples from this client and was able to increase recovery of the gold from concentrate to over 90% at a lab scale using the technology, compared with approximately 71% using cyanide. Thiosulphate leaching is another route often highlighted in the discussion of processing MEET US! 52$67,1*'(9,&( &203/(7(3/$17/$<287 MINING METALS CENTRAL ASIA 18-20 SEPTEMBER 2019 ALMATY KAZAKHSTAN 79 GOLD Au 196.96 CIL TAILINGS OXIDISING ROASTING 3,/273/$177(676Ɣ(1*,1((5,1*Ɣ352&85(0(17Ɣ&216758&7,21Ɣ6(59,&( dobersek.com