iDentistry The Journal January 2017 | Page 7

The Journal However, PEEK dental implants have not been extensively used clinically and there is insufficient data to deduce their long-term efficacy in human subjects. • PEEK as a removable prosthesismaterial Dentures can be constructed by using PEEK computer-aided design and computer-aided manufacture systems [16] . Tan-nous et al. [17] has suggested that denture clasps made of PEEK have lower retentive forces compared to [18] cobalt–chromium (Co–Cr) clasps . However, since the study was conducted on metal crowns in vitro, it is not known how effective the esthetic PEEK clasps would be in retaining dentures in the clinical setting. Another application of PEEK is the construction of a removable obturator [19] . Nevertheless, more studies are needed to evaluate the efficacy of PEEK obturators compared to conventional acrylic prostheses. To date, no clinical studies or systematic reviews focusing on the use of PEEK dentures have been published. However, owing to the superior mechanical and biological properties of PEEK, it will not be surprising if dentures constructed from the polymer are routinely constructed in near future. • PEEK crowns A variety of procedures have been suggested to condition the surface of PEEK in order to facilitate its bonding with resin composite crowns. Even though air abrasion with and without silica coating creates a more wettable surface [20] , etching with sulphuric acid creates a rough and chemically altered surface which enables it to bond more effectively with hydrophobic resin composites [21] . It has been observed that etching with sulfuric acid for 60–90s can exhibit shear bond strength to resin composite cements as high as 15.3 MPa after [22] being stored in water for 28 days at 370C . Etching with piranha acid and using a bonding agent have been shown to produce tensile bond strength to composite resin as high as 23.9 MPa in aged PEEK specimens [23]. No significant 10 3 1 16 6 differences were observed in the tensile bond strength of PEEK crowns and dentin abutments using air abrasion and sulfuric acid etching [24] techniques . These studies suggest that PEEK can be used under resin-composite as a coping material. Because the mechanical properties of PEEK are similar to those of dentin and enamel, PEEK could have an advantage over alloy and ceramic restorations. • PEEK CAD-CAM milled fixed partial dentures Using CAD-CAM to manufacture restorations makes it possible to produce dental prostheses chair-side [25] . CAD-CAM designed composites and polymethylmethacrylate (PMMA) fixed dentures have superior mechanical properties compared to conventional fixed dentures [26] . PEEK is another material that can be used an alternative to PMMA for CAD-CAM restorations. Three-unit PEEK fixed partial denture manufactured via CAD-CAM has been suggested to have a higher fracture resistance than pressed granular- or pellet-shaped PEEK dentur es [27] . The fracture resistance of the CAD-CAM milled PEEK fixed dentures is much higher than those of lithium disilicate glass-ceramic (950N), alumina (851N) [28] , zirconia (981-1331N) [29] . The abrasive properties of PEEK are excellent. Despite of significantly low elastic moduli and hardness, abrasive resistance of PEEK is [30] competitive with metallic alloys . However, no clinical studies have attempted to compare the abrasion produced by PEEK crowns on teeth to that produced by other materials such as alloys and ceramics. Hence, it is still unknown if PEEK crowns can function efficiently in harmony with dentin and enamel. Considering good abrasion resistance, mechanical attributes and aforementioned adequate bonding to composites and teeth, a PEEK fixed partial denture would be expected to have a satisfactory survival rate. Vol. 13 12 No. 1 2 3 May-August Sept-Dec 2017 Jan-April 2016 2016