Hydrogen Tech World February 2025 | Page 34

[ e-methanol ]
Compressor
Pressurized Feed gas
Steam drum
Steam
Off-gas
Purge
HRU
H 2
Unconverted Feed gases
Crude methanol separator
Recycle Feed gases
Cooler
Heat Exchanger
Reactor effluent
Wet Steam
Steam
Boiling Water Reactor ( BWR )
Water make-up Reactor cooling
Cross-sectional view of a distillation column
Crude methanol
Catalyst for e-methanol production ( Topsoe ยด s MK-417 Sustain )
Topping Column
Condenser
Reflux
Distillation lights
Reflux drum
Pressure Column
Refining Column
Condenser
Reflux
Recovery Column Vent
Reflux drum
Crude methanol
Reboiler
Steam Steam return
Reboiler
Steam Steam return
Reboiler
Fusel oil
Residual water
Pure methanol
Figure 3 . Process flow diagram of the e-methanol production process
refining , eliminating possible heavy by-products such as fusel oil ( a mixture of undesired alcohols ) and water .
column reboiler by condensation . This reduces the net energy requirement of the purification system ( Figure 3 ). 4
On the other hand , there is the possibility of using three distillation columns . This alternative is more expensive in terms of investment but more economical in terms of operational costs , as it reduces the heat demand via heat integration . In this distillation strategy , the topping column is accompanied by two columns : a pressure column and a refining column . The pressure column is operated at a higher pressure than the refining column , and the product from the topping column heads ( methanol vapor ) can be used to provide the necessary heat to the refining
Finally , a single distillation column can be installed for methanol purification if it is to be used as a fuel . This configuration would result in a lower methanol purity but high enough to be used as a fuel for energy purposes ( 95 % vol .). 4
Costs and consumptions of e-methanol plants
Methanol plants investments are not negligible ; however , in a Power to X plant , these can still represent less than 30 % of the total investment compared to the
34 Hydrogen Tech World | Issue 20 | February 2025