[ e-methanol ]
Compressor |
Pressurized Feed gas |
Steam drum |
Steam |
Off-gas |
Purge
HRU
H 2
Unconverted Feed gases
Crude methanol separator
|
Recycle Feed gases
Cooler
Heat Exchanger
|
Reactor effluent |
Wet Steam
Steam
Boiling Water Reactor ( BWR )
|
Water make-up Reactor cooling |
Cross-sectional view of a distillation column |
Crude methanol |
Catalyst for e-methanol production ( Topsoe ยด s MK-417 Sustain ) |
Topping Column |
Condenser
Reflux
|
Distillation lights
Reflux drum
Pressure Column
|
Refining Column |
Condenser
Reflux
Recovery Column Vent
Reflux drum
|
Crude methanol |
|
|
|
|
Reboiler
Steam Steam return
|
Reboiler
Steam Steam return
|
Reboiler |
Fusel oil
Residual water
|
Pure methanol
Figure 3 . Process flow diagram of the e-methanol production process
refining , eliminating possible heavy by-products such as fusel oil ( a mixture of undesired alcohols ) and water .
column reboiler by condensation . This reduces the net energy requirement of the purification system ( Figure 3 ). 4
On the other hand , there is the possibility of using three distillation columns . This alternative is more expensive in terms of investment but more economical in terms of operational costs , as it reduces the heat demand via heat integration . In this distillation strategy , the topping column is accompanied by two columns : a pressure column and a refining column . The pressure column is operated at a higher pressure than the refining column , and the product from the topping column heads ( methanol vapor ) can be used to provide the necessary heat to the refining
Finally , a single distillation column can be installed for methanol purification if it is to be used as a fuel . This configuration would result in a lower methanol purity but high enough to be used as a fuel for energy purposes ( 95 % vol .). 4
Costs and consumptions of e-methanol plants
Methanol plants investments are not negligible ; however , in a Power to X plant , these can still represent less than 30 % of the total investment compared to the
34 Hydrogen Tech World | Issue 20 | February 2025