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Hydrogen Applications

Thermal management in green hydrogen production : Design considerations

Central cooling systems for large-scale green hydrogen production can be based on wet or dry cooling . Alternatively , hybrid solutions are available as well . This article discusses three such solutions and considers the factors influencing the selection of cooling technology .
About the company
Kelvion Thermal Solutions ( KTS ) is an expert in heat exchange . KTS normally gets involved in early engineering phases of large projects to help clients in making such technology choices .
By Roy Niekerk , Director Global Sales & Solutions Hydrogen , and Radhouene Manita , Application Engineer , Kelvion Thermal Solutions
The two most established processes for green hydrogen production are alkaline water electrolysis and polymer electrolyte membrane ( PEM ) electrolysis . In both processes , a liquid is recirculated over an electrolyser stack to form hydrogen and oxygen . During the electrolysis process , heat is released , which needs to be cooled away . This cooling step is normally done in a plate and frame heat exchanger . However , more cooling positions in the hydrogen production process are available . Alternating current electricity is changed into direct current , which releases heat . Two further positions are the formed oxygen and hydrogen , which are cooled before further purification . The deeper the cooling , the more water is ‘ knocked out ’ by means of condensation , reducing the required size of the drying section in the plant . Further downstream , the hydrogen is compressed , which requires compression interstage and aftercoolers . A closed loop of water or water-glycol mixture is used to cool all the different coolers in the hydrogen production process . And the closed loop is cooled in a central system . Electrolyser capacity is normally expressed in megawatts . And as a rule of thumb , roughly 25 – 30 % of that capacity is cooled away in the central cooling system . Different cooling methods exist .
Dry or wet cooling Air Fin Coolers ( AFC ) are one method of cooling down a closed loop . Typically , an AFC consists of a series of horizontal finned tube bundles with box headers at each end that run either underneath or above axial fans within a plenum chamber , which directs the air flow . Usually , the air blows upwards through the tube bundles , cooling the hot liquid . But the fans can be configured to forced or induced draft , depending on whether the air is pushed or pulled through the tube bundle . Large-size industrial AFCs offer a great design freedom in terms of plot configurations , header types , and project specifications that need to be followed . A big advantage is that no water is used . As a rule of thumb , the temperature approach in an AFC is 10 ° C . By using special tube technologies such as Groovy-Fin ® and DIESTA ® , the temperature approach can in some cases be pushed to 7 ° C , but it is not advisable to use such low values in the initial project development . As an example , if a project designs the system for maximum 30 ° C dry-bulb temperature and Groovy fins are used with 7 ° C approach temperature , the closed loop can be cooled down to 37 ° C as a minimum . Temperature approach in a plate and frame exchanger is 2 ° C . The resulting minimum process temperature is therefore 39 ° C . In regions where water is available , however , open cooling towers can be selected . Water that is sprayed down in the tower is brought in contact with air , which is pulled through the tower fill material by means of a large fan-motor combination . A very small portion of water is evaporated , causing the remaining water to cool down . A big advantage of a cooling tower are the much lower temperatures it can reach compared to dry cooling . In the above-given example , a dry-bulb temperature of 30 ° C was assumed , which is a typical value for Western European locations . In such locations , however , the wet-bulb temperature can be as low as 21 ° C . A rule of thumb for cooling towers is a 4 ° C approach to wet-bulb temperature . In this case ,
Demineralised water
Purification section
Pump
Pump
Plate heat
Filter
Electrolyser
exchanger
Stack
H2 Separator
O2 Separator
Plate heat exchanger
Moisture separator
Purge
Purification section
H2
Plate heat exchanger
Purge
Moisture separator
O2
Electrolysis process scheme
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