Expert Solutions Purity & Specialty Issue 21 | Page 12

REDUCE THE COST OF REFLOW FURNACE APPLICATIONS A LOW OXYGEN (O 2 ) CONCENTRATION IN REFLOW FURNACES DELIVERS A HIGHER QUALITY PRODUCT, REDUCES DEFECTS, AND LOWERS MAINTENANCE COSTS, POTENTIALLY SAVING OPERATORS THOUSANDS OF DOLLARS. WHY MEASURE O 2 IN THE FURNACE? Traditionally, printed circuit boards (PCBs) were cleaned with chlorofluorocarbon (CFC) based compounds. However, with the widespread elimination of CFCs, PCB manufacturers must now create an inert environment in the solder furnace to reduce O 2 concentration. In wave soldering, the PCB is passed over a cylinder of molten solder. In the reflow process, the PCB is pre-pasted with solder, then passed through a pre-heater, allowing the solder to run onto the components and hold them in place. The presence of O 2 in the reflow furnace can compromise the wetting properties of the solder as it flows, causing poor solder joints, so the O 2 level in the furnace must be monitored. THE DRAWBACKS OF TRADITIONAL SENSORS EXCEPTIONALLY ACCURATE O 2 ANALYSIS Galvanic sensors have traditionally been used to monitor O 2 in reflow furnaces. These have a short lifespan – typically a few months – because they use a lead anode and silver cathode, which are consumed in the measurement process. Using Servomex’s non-depleting Coulometric sensor, the SERVOPRO MonoExact DF150E provides an effective solution for reflow O 2 analysis that avoids the problems associated with galvanic or Zirconia sensors for this application. Ensuring accuracy with no sensor drifting and no false low readings, it provides highly effective protection against inerted material oxidization. This supports excellent product batch quality and significantly improves nitrogen consumption. It uses carbon electrodes which are not affected by chemical changes, and so does not need periodic replacement, nor does it produce false low readings, as there is no loss of measurement sensitivity or reaction with sample gas components. The MonoExact DF150E can be easily integrated into multiple zone sample systems using a manual or automatic sequencing system. This makes it ideal for OEM furnace manufacturers who supply analyzers as an option or as standard for the end-user, heat treatment contractors and on-site or laboratory processes. As the cell depletes, measurements become less accurate. For galvanic sensors, low expectancy is a function of usage – they eventually Lead Anode (Depleting) PbO OH- Silver Cathode Membrane KOH Electrolyte O 2 (Dissolved) O 2 (Gas Phase) GALVANIC SENSOR P12 Gas Sample read low as the electrode sites are depleted and sensitivity is reduced. The effect of trace level acid gases – generated by the flux on the PCBs – on the silver cathode means that these analyzers also require frequent recalibration, and regular sensor replacement. Without this, the analyzer will give falsely low readings, resulting in poor quality or scrap product. A permeable membrane separates the gas sample from the electrolyte, allowing the O 2 ions to migrate into solution. If the sensor is exposed to an over-range condition, such as the solder system hood being opened, the membrane will saturate with oxygen from ambient air. It can take several hours for oxygen to return to parts-per-million (ppm) levels. Zirconia sensors are not suited to this application, because any reducing gases (those that can be oxidized, such as carbon monoxide, hydrogen, methane and hydrocarbons) significantly interfere with the measurement. Due to the high temperature of the sensor, the O 2 is reacted with hydrocarbons that are given off by the flux in the furnace. This reacted O 2 is not being measured, so the sensor gives false readings that result in poor quality welding. ZIRCONIA OXIDE SENSOR The fast response offered by the Coulometric sensor gives an immediate indication of changes in O 2 , regardless of whether they are caused by an ambient air leak or incorrect nitrogen (N 2 ) inerting levels. See pages 04-05: for a description of the Coulometric process See pages 10-11: for more about the MonoExact DF150E SERVOPRO MonoExact DF150E TRACE OXYGEN ANALYZER KEY BENEFITS OF THE COULOMETRIC SENSOR NO periodic replacement NO reaction with the sample NO false low readings NO loss of measurement sensitivity P13