Encyclopedie de la recherche sur l'aluminium au Quebec - Edition 2014 | Seite 23

PRODUCTION DE L’ALUMINIUM // ALUMINIUM PRODUCTION Relationship between the chemical and the diffusionENTRE LES RÉACTIVITÉS CHIMIQUES ET SOUS DIFFUSION reactivities RELATION of carbon anode under CO2 at 960 C D'UNE ANODE EN CARBONE VIS-À-VIS DU CO2 À 960 oC 21 O Relation entre les réactivités chimique et RELATIONSHIP BETWEEN sous diffusion d’une anode en carbone THE CHEMICAL AND THE DIFFUSION REACTIVITIES OF CARBON ANODE UNDER CO2 AT 960 oC vis-à-vis du CO2 à 960 C O F.Chevarin1,2, L. Lemieux1,2, D. Ziegler3, M.Fafard2, H. Alamdari1,2 1Department of Mining, Metallurgical and Materials Engineering, 1065 avenue de la Médecine Université Laval, Québec, QC, G1V 0A6, Canada MODELLING OF ALUMINIUM CELL AND ELECTRICAL ENERGY Industrial Research Chair MACE3 and Aluminium Research Centre – REGAL EFFICIENCY Université Laval, Québec, QC, G1V 0A6, Canada 3Alcoa Primary Metals, Alcoa Technical Center, 100 Technical Drive, Alcoa Center, PA,15069-0001, USA 2NSERC/Alcoa 1. Introduction 2. Objectives Carbon anode used in the Hall-Héroult electrolysis process is gasified according to the Boudouard reaction (CO2+C→2CO). A gradient of concentration is created due to the limitations of the CO2 gas diffusion through the anode porosity during its gasification. The