Cold Link Africa September 2020 | Page 31

INCORPORATING COLD CHAIN FEATURE R143a and R125, with a relatively low proportion of R134a, the temperature glide with the ternary blend R404A within the relevant application range is less than one Kelvin. The characteristics within the heat exchangers are therefore not very different than with azeotropes. The results obtained from heat transfer measurements show favourable conditions. R507A is a binary substance combination which even gives an azeotropic characteristic over a relatively wide range. The conditions therefore tend to be even better. The performance (Figure 6) gives hardly any difference between the various substances and is very similar to R502. This also explains the high market penetration of these refrigerants. With regard to the thermodynamic properties, they are particularly suitable for commercial medium and low temperature systems. Typical metallic materials are compatible with HFC refrigerants. Elastomers, however, must be adapted to the changed characteristics. Suitable lubricants are polyol esters. The relatively high global warming potential (GWP = 3922 .. 3985), which is mainly determined by the R143a and R125, is something of a hitch. However, it is better than R502 and with regard to the favourable energy demand also leads to a reduction of the TEWI value. Other improvements are possible in this respect due to further developed system control. Nevertheless, due to their high global warming potential (GWP), the use of R404A and R507A will no longer be allowed in the EU in new installations from 2020. This has been settled in the F-Gas Regulation No. 517/2014 to be applied since 2015. However, the current requirement of phase-down in connection with a strict quota system will lead to an earlier phase-out in many applications. In the USA, Canada and Australia there are also requirements to phase-out R404A and R507A. For an international phase-down (starting in 2019) of HCFC and HFC refrigerants, the so-called Kigali Amendment was agreed upon in 2016 as part of the Montreal Protocol. The system technology can be based on the experience with R22 and R502 over a wide area. On the thermodynamic side, a heat exchanger between the suction and liquid line is recommended as this will improve the refrigerating capacity and COP. CLA To be continued in the next issue of Cold Link Africa COLD LINK AFRICA • September 2020 www.coldlinkafrica.co.za 31