Cold Link Africa January/February 2018 | Page 43

FEATURE INCORPORATING COLD CHAIN Continued from page 41 With his many years of experience in the foaming sector, Alan Yeates was contracted by UNIDO to assist in the phase out of R141b. He relates the steps towards zero R141b usage. UNIDO TECHNICAL ASSISTANCE The phase out of HCFC-141b, used as the primary blowing agent in rigid insulation foam and microcellular integral skin foam, was prioritised by the project to maximise ODP reduction. In 2010, the baseline consumption volume for these applications was determined to be 1 656 metric tonnes (mt) with an ODP value of 182.2 metric tonnes. The foam sector is complex; therefore, to meet the country’s targeted commitment to the phase- out programme of all ODS-containing substances, the majority of the required phase out was achieved either through systems house conversion and downstream modifications, or in the case of larger consumers, the conversion to alternative foaming agents. The revised target date of 1 January 2016, the firm indication of the government’s commitment to ban imports of HCFC-141b, both pure and contained in pre-blended polyols, has also been established. To put it across, the plan of action was agreed between the Department of Environmental Affairs (DEA) that acts as the National Ozone Unit in South Africa, and UNIDO, the implementing agency, and consisted of four stages, namely: • Stage I: Identification of alternative technologies to replace HCFC-141b; their availability on the market; and capability of the local industry to At CIP: Nic Carpenter and Alan Yeates (right). suitable for large-scale use, whereas methyl formate, also highly flammable LIMITED OPTIONS FOR PRE-BLENDED packaging, as well as construction In conclusion, all technologies are and insulation subsectors of the foam in pure state but safe in blend, bears available from the chemical suppliers manufacturing sector, was provided. low cost for conversion and is suitable in South Africa, but for most of pre- By large, the systems house Resikem for medium to small enterprises. HFA blended system users, the only Benoni underwent the conversion to 245/365, applicable for medium-sized alternatives are methyl formate or HFA facilitate the production of methyl enterprises, is safe in blend albeit costly 245/365 blends. formate pre-blended polyols systems and has zero ODP; yet, it has GWP. Lastly, The objectives of Stage II of the action and, therefore, received funding for formic acid, added as third component, plan were also attained. Hence, a needs procuring storage tanks, pumps, and is suitable for large-scale use but has assessment of the self-blenders and ancillaries needed. Based on the data of short shelf life. Water-blown systems still systems houses was carried out and the 2010, the overall phase out of 120mt of remain available for specialised use. financial assistance covering appliances, HCFC-141b has been achieved by Resikem. develop substitute polyurethane foam systems to replace currently used HCFC-141b foam systems. • Stage II: A needs assessment of the self-blenders and systems blending houses to be determined. Financial assistance to be provided for the equipment, enabling the development of foam systems by using alternative blowing agent technologies where needed. • Stage III: Process evaluation by means of small-scale trials to be carried out by the end users of the alternative blowing agent foam technologies. Financial assistance to be provided for the modification of the process or plant where needed. • Stage IV: Commercialisation and implementation of chosen foam technology by the end of 2015. As a result, a market survey to determine industry requirements was completed, and four replacement technologies, though not all suitable for all applications, were identified under Stage I of the action plan. For instance, cyclopentane, highly flammable and rather costly in terms of conversion, is Foaming equipment at Insulated Structures. COLD LINK AFRICA • January | February 2018 www.coldlinkafrica.co.za 43