Chemistry Today Jun. 2014 | Page 3

Economics

Increased regulation of electronic waste and concern over the environmental harm in mature economies has created an economic disincentive to remove residues prior to export. Critics of trade in used electronics maintain that it is still too easy for brokers calling themselves recyclers to export unscreened electronic waste to developing countries, such as China, India and parts of Africa, thus avoiding the expense of removing items like bad cathode ray tubes (the processing of which is expensive and difficult). Developing countries have become toxic dump yards of e-waste.

Defenders of the trade in used electronics say that extraction of metals from virgin mining has been shifted to developing countries. Recycling of copper, silver, gold, and other materials from discarded electronic devices is considered better for the environment than mining. They also state that repair and reuse of computers and televisions has become a "lost art" in wealthier nations, and that refurbishing has traditionally been a path to development.

Toxicity & Environemental Impact

E-waste has many types of poisons built into it. Some of these toxic substances are what make the devices safe when they operate. Cathode-ray-tube televisions and computer monitors, have large amounts of lead built into the glass to stop stray radiation from escaping. If these old TVs and PCs are improperly discarded at the dump, they can shatter and release dangerous amounts of lead into the ground and eventually into the water table. Extreme care must be taken to remove the lead from the glass and dispose of it in an ecologically sound manner.

Semiconductors in computer chips and modern circuitry also contain many poisons, including gallium arsenide, cadmium, and beryllium. Mercury is sometimes used in switches. PVC, a known carcinogen, is used in the plastic coatings of the wires and cables, and brominated flame retardants are included in other plastics, such as the outer casing of processors. If these products are burned, or destroyed and turned into dust—as happens in some low-tech developing-world recycling operations—they release highly toxic substances into the atmosphere. If they’re thrown into landfills and allowed to break down over time, they release the same poisons into the land and possibly into the water table.

One study of environmental effects in Guiyu, China found the following:

• Airborne dioxins – one type found at 100 times levels previously measured

• Levels of carcinogens in duck ponds and rice paddies exceeded international standards for agricultural areas and cadmium, copper, nickel, and lead levels in rice paddies were above international standards

• Heavy metals found in road dust – lead over 300 times that of a control village’s road dust and copper over 100 times

Cathode Ray Tubes, as of 2009, were the most common type of E-Waste. As you can see above, they are also one of the most toxic.