ALS Product catalogues AIR | Page 18
Persistent Organic Pollutants (POPs)
Polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/F)
Parameter
2,3,7,8-PCDD/F congeners
Other congeners
2,3,7,8-TCDD OCDD 1,2,3,7,8,9-HxCDF tetra-CDD hexa-CDF
1,2,3,7,8-PeCDD 2,3,7,8-TCDF 2,3,4,6,7,8-HxCDF penta-CDD hepta-CDF
1,2,3,4,7,8-HxCDD 1,2,3,7,8-PeCDF 1,2,3,4,6,7,8-HpCDF hexa-CDD 1,2,3,6,7,8-HxCDD 2,3,4,7,8-PeCDF 1,2,3,4,7,8,9-HpCDF hepta-CDD 1,2,3,7,8,9-HxCDD 1,2,3,4,7,8-HxCDF OCDF tetra-CDF 1,2,3,4,6,7,8-HpCDD 1,2,3,6,7,8-HxCDF I-TEQ penta-CDF
Minimum sample amount:
components (sorbent PUF/XAD, filter, condensate, rinsate, wipes)
representing one emission sampling, minimum 4 m 3 , optimum 10 m3
Method:
EN 1948-2,3 (HRGC-HRMS), US EPA 23 (HRGC-HRMS)
Note:
•
LOQ for I-TEQ is 2 pg 2,3,7,8-TCDD/m 3 (sampling of 10 m 3 ), results can be expressed in toxicity equivalent
according to WHO
•
Calculation parameter TEQ is mentioned at the levels of „lowerbound“ and „upperbound“
Polychlorinated biphenyls (PCB) – Coplanar PCB (dioxin-like PCB) and indicator PCB
Parameter
Parameter
NON-ORTHO PCB
Parameter
MONO-ORTHO PCB
PCB 77 PCB 105 PCB 156
PCB 81 PCB 114 PCB 157
PCB 126 PCB 118 PCB 167
PCB 169 PCB 123 PCB 189
DI-ORTHO PCB
INDICATOR PCB
PCB 170 PCB 28 PCB 138
PCB 180 PCB 52 PCB 153
WHO-TEQ PCB 101 PCB 180
PCB 118 sum of PCB – 7 congeners
Minimum sample amount:
components (sorbent PUF/XAD, filter, condensate, rinsate, wipes)
representing one emission sampling, minimum 4 m 3 , optimum 10 m 3
Method:
EN 1948-4 (HRGC-HRMS)
Note:
•
LOQ for coplanar PCB expressed by WHO-TEQ is 0.07 pg 2,3,7,8-TCDD/m 3 , for the sum of PCB – 7 congeners,
the LOQ is 0.34 ng/m 3 (sampling of 100 m 3 )
•
Calculation parameter TEQ is mentioned at the levels of „lowerbound“ and „upperbound“
Polycyclic aromatic hydrocarbons (PAH) by HPLC
Parameter
Parameter
benzo(b)fluorantene* benzo(a)pyrene*
indeno(1,2,3-cd)pyrene* benzo(k)fluorantene*
Parameter
Sum of 4* PAH
OTHER PAH
pyrene acenaphtylene fluorene
benzo(a)antracene acenaphtene phenantrene
chrysene dibenzo(a,h)antracene antracene
naphtalene benzo(g,h,i)perylene fluorantene
Minimum sample amount:
components (sorbent PUF/XAD, filter) representing one emission sampling,
minimum 4 m 3 , optimum 20 m 3
Method:
HPLC/UV-FLD
Note:
LOQ for sum of 4* PAH is (sampling of 20 m 3 ) 14 ng/m 3
18
Product catalogue Air/emission
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