2016-2017 | Page 51

REMOVAL OF SAFRANIN FROM THE ENVIRONMENT BY USING GRAPHENE OXIDE PAPER Question: Can Graphene Oxide be used to remove dyes from the environment? Introduction: Water pollution is threatening all living organisms in the world. The main source of this problem is the indifference of companies which have factories. Because they need to use dyes for coloring, they are polluting rivers, oceans and lakes. They dump dyes from factories into water sources because they don’t know how to remove them in a satisfactory way. (http://www.nationalgeographic.com/environment/ freshwater/pollution/) One of the most dangerous dyes is safranin. Safranin is a red dye matter, and its formula is C20H19N4Cl (Fig. 1). Safranin is used in textile, cosmetic and paper industries. It affects the structure of bacteria, so it may affect beneficial bacteria, too. Thus, it causes problems for the environment. (Preethi, Sivanesan, Sivasamy, & Swaminathan, 2006 ; Rotte, Yerramala, Boniface, & Srikanth, 2014) Graphene is one atom thick carbon material, which is used in advanced technologies such as membrane, sensor, battery and electronics. Graphene is prevalently produced from graphite by its oxidation (Fig. 2). Fig. 2. a) Graphene, b) Graphite, c) Graphene oxide (www.emaze.com/@ACCCFZLC/Graphene-Presntation, www.graphene-info.com/graphene-oxide ) Data: SEM: SEM image of the prepared graphene oxide paper is presented in Fig. 7. Graphene oxide paper has a wrinkled surface (Fig. 7a). Additionally, it is seen in Fig. 7.b that the paper formed layer by layer assembly after vacuum filtration process. CHEMISTRY DEPARTMENT Fig. 1. Chemical formula and aqueous solution of safranin Fig. 3. Top-view (a) and cross-sectional (b) SEM images of graphene oxide paper (Alanyalioglu & Dagci, 2016) THE CLAPPER 2016 - 2017 51